Robert A. Riggleman

Principal Investigator

Google Scholar

Associate Professor of Chemical and Biomolecular Engineering


  • B.S. Engineering, University of South Carolina, 2002
  • Ph.D. Chemical and Biological Engineering, University of Wisconsin-Madison, 2007

Postdoctoral training:

  • Chemical and Biological Engineering, University of Wisconsin-Madison, 2007-2008
  • Chemical Engineering, University of California-Santa Barbara, 2009-2010


  1. Understanding Creep Suppression Mechanisms in Polymer Nanocomposites through Machine Learning
  2. MATILDA.FT, A mesoscale simulation package for inhomogeneous soft matter
  3. Experimental observations of fractal landscape dynamics in a dense emulsion
  4. The effect of monomer polarizability on the stability and salt partitioning in model coacervates
  5. Exploring the relationship between softness and excess entropy in glass-forming systems
  6. Bicontinuous interfacially jammed emulsion gels with nearly uniform sub-micrometer domains via regulated co-solvent removal
  7. Increases in Miscibility of a Binary Polymer Blend Confined within a Nanoparticle Packing
  8. Failure and Mechanical Properties of Glassy Diblock Copolymer Thin Films
  9. Exploring canyons in glassy energy landscapes using metadynamics
  10. Structuro-elasto-plasticity model for large deformation of disordered solids
  11. Percolation of co-continuous domains in tapered copolymer networks
  12. Decoupling the Impact of Entanglements and Mobility on the Failure Properties of Ultrathin Polymer Films
  13. The Role of Intra-molecular Relaxations on the Structure and Stability of vapor-Deposited Glasses
  14. Effect of Graft Length and Matrix Molecular Weight on String Assembly of Aligned Nanoplates in a Lamellar Diblock Copolymer
  15. Predicting the unobserved. A statistical mechanics framework for non-equilibrium material response with quantified uncertainty
  16. Role of Local Structure in the Enhanced Dynamics of Deformed Glasses
  17. Fracture of model end-linked networks
  18. Thickness-Dependent Mechanical Failure in Thin Films of Glassy Polymer Bidisperse Blends
  19. Lewis Adduct-Induced Phase Transitions in Polymer/Solvent Mixtures
  20. Load-bearing entanglements in polymer glasses
  21. Investigating Nanoparticle Organization in Polymer Matrices during Reaction-Induced Phase Transitions and Material Processing
  22. Effect of surface properties and polymer chain length on polymer adsorption in solution
  23. Chain and Segmental Dynamics in Polymer–Nanoparticle Composites with High Nanoparticle Loading
  24. Coarse-Grained Modeling of Polymer Nanocomposites: Field-Theoretic Simulations [Book Chapter]
  25. Conformation and dynamics of ring polymers under symmetric thin film confinement
  26. Dynamic phase transitions in freestanding polymer thin films
  27. Polymer Conformations and Diffusion through a Monolayer of Confining Nanoparticles
  28. Molecular View of Cavitation in Model-Solvated Polymer Networks
  29. Cavitation in Soft Matter
  30. Origin of Mechanical Enhancement in Polymer Nanoparticle (NP) Composites with Ultrahigh NP Loading
  31. Effect of Polymer-Nanoparticle Interactions on Solvent-driven Infiltration of Polymer (SIP) into Nanoparticle Packings: a Molecular Dynamics Study
  32. Experiments and Simulations Probing Local Domain Bulge and String Assembly of Aligned Nanoplates in a Lamellar Diblock Copolymer
  33. Equilibrium Field Theoretic Study of Nanoparticle Interactions in Diblock Copolymer Melts
  34. Increased Polymer Diffusivity in Thin-Film Confinement
  35. Distinguishing failure modes in oligomeric polymer nanopillars
  36. Phase Behavior of Grafted Polymer Nanocomposites from Field-Based Simulations
  37. Identifying structural signatures of shear banding in model polymer nanopillars
  38. Effects of microstructure formation on the stability of vapor-desposited glasses
  39. Polymer Conformations and Dynamics under Confinement with Two Length Scales
  40. Critical Contact Angle to Induce Capillary Rise of Polymers in Nanopores Does Not Depend on Chain Length
  41. Polymer Diffusion Is Fastest at Intermediate Levels of Cylindrical Confinement
  42. Effect of substrate interactions on the glass transition and length-scale of correlated dynamics in ultra-thin molecular glass films
  43. Emerging investigators in materials science 2017-2018
  44. Field-Theoretic Simulations of the Distribution of Nanorods in Diblock Copolymer Thin Films
  45. Structure-property relationships from universal signatures of plasticity in disordered solids
  46. Inverse design of grafted nanoparticles for targeted self-assembly
  47. Comparison of Field-Theoretic Approaches in Predicting Polymer Nanocomposite Phase Behavior
  48. Nanorod Mobility Influences Polymer Diffusion in Polymer Nanocomposites
  49. Perspective: Outstanding theoretical questions in polymer-nanoparticle hybrids
  50. Grafted polymer chains suppress nanoparticle diffusion in athermal polymer melts
  51. Field-theoretic simulations of block copolymer nanocomposites in a constant interfacial tension ensemble
  52. Nanoporous Polymer-Infiltrated Nanoparticle Films with Uniform or Graded Porosity via Undersaturated Capillary Rise Infiltration
  53. Solvent vapor annealing in block copolymer nanocomposite films: a dynamic mean field approach
  54. Long-range correlated dynamics in ultra-thin molecular glass films
  55. Understanding soft glassy materials using an energy landscape approach
  56. Isolating the Effect of Molecular Weight on Ion Transport of Non-Ionic Diblock Copolymer/Ionic Liquid Mixtures
  57. Engineering the Assembly of Gold Nanorods in Polymer Matrices
  58. Dispersion and alignment of nanorods in cylindrical block copolymer thin films
  59. Attraction of Nanoparticles to Tilt Grain Boundaries in Block Copolymers
  60. The dynamics of unentangled polymers during capillary rise infiltration into a nanoparticle packing
  61. Local Polymer Dynamics and Diffusion in Cylindrical Nanoconfinement
  62. Predicting the structure and interfacial activity of diblock brush, mixed brush, and Janus-grafted nanoparticles
  63. Entanglement Reduction and Anisotropic Chain and Primitive Path Conformations in Polymer Melts under Thin Film and Cylindrical Confinement
  64. The distribution of homogeneously grafted nanoparticles in polymer thin films and blends
  65. Understanding Plastic Deformation in Thermal Glasses from Single-Soft-Spot Dynamics
  66. Strain localization in glassy polymers under cylindrical confinement
  67. Size-Controlled Self-Assembly of Superparamagnetic Polymersomes
  68. Field theoretic simulations of polymer nanocomposites
  69. Effect of particle size and grafting density on the mechanical properties of polymer nanocomposites
  70. Influence of Backbone Rigidity on Nanoscale Confinement Effects in Model Glass-Forming Polymers
  71. Evolution of collective motion in a model glass-forming liquid during physical aging
  72. Heterogeneous Segmental Dynamics during Creep and Constant Strain Rate Deformations of Rod-Containing Polymer Nanocomposites
  73. Investigation of the interfacial tension of complex coacervates using field-theoretic simulations
  74. Dynamics and Deformation Response of Rod-Containing Nanocomposites
  75. Influence of Chain Stiffness on Thermal and Mechanical Properties of Polymer Thin Films
  76. Influence of Nanorod Inclusions on Structure and Primitive Path Network of Polymer Nanocomposites at Equilibrium and Under Deformation
  77. Mechanical properties of antiplasticized polymer nanostructures
  78. Field-theoretic simulations in the Gibbs ensemble
  79. Antiplasticization and the elastic properties of glass-forming polymer liquids
  80. Heterogeneous dynamics during deformation of a polymer glass
  81. Entanglement network in nanoparticle reinforced polymers
  82. Fluorinated Quaternary Ammonium Salts as Dissolution Aids for Polar Polymers in Environmentally Benign Supercritical Carbon Dioxide
  83. Deformation-Induced Mobility in Polymer Glasses during Multistep Creep Experiments and Simulations
  84. Dynamics of a Glassy Polymer Nanocomposite during Active Deformation
  85. Nonlinear Creep in a Polymer Glass
  86. Antiplasticization and local elastic constants in trehalose and glycerol mixtures
  87. Molecular plasticity of polymeric glasses in the elastic regime
  88. Free Volume and Finite-Size Effects in a Polymer Glass under Stress
  89. Characterization of the potential energy landscape of an antiplasticized polymer
  90. Tuning polymer melt fragility with antiplasticizer additives
  91. Influence of Confinement on the Fragility of Antiplasticized and Pure Polymer Films